Post by Kaya on May 4, 2012 12:16:05 GMT -8
So Shoki asked me about it in the cbox and I thought I'd present my initial findings in a thread for easy viewing.
Additionally, we are a fantasy role play and have birds that heal people by singing. Just saying.
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In the canon of Dragonriders of Pern, it is said that Firestone is a phosphine bearing rock.
As per Wikipedia,
Phosphine is the compound with the chemical formula PH3. It is a colorless, flammable, toxic gas.
The wikipedia page on Phosphines also lists them as a fire diamond health hazard 4 (the highest rating "very deadly"), which let me tell you as a chemist is something that I would do a lot to avoid coming into contact with. It's classified as Highly flammable (F+), Very toxic (T+), Corrosive (C), and Dangerous for the environment (N).
Overexposure to phosphine gas causes nausea, vomiting, abdominal pain, diarrhea; thirst; chest tightness, dyspnea (breathing difficulty); muscle pain, chills; stupor or syncope; pulmonary edema.
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So let's start with the fact that firestone as a tool is already seeming improbable in itself.
Then I looked into "spontaneous endothermic reactions" looking for something that would occur on its own and cool down itself and the surrounding area. Turns out you can already see this happen in everyday items. Have you ever had an "instant cold pack"? Spontaneous endothermic reaction.
The general reaction used by the cold packs is:
NH4Cl + H2O
or
NH4NO3 + H2O (I think this one has been discontinued in packs due to the more health hazardous nature of NH4NO3 as opposed to NH4Cl).
NH4Cl's fire diamond gives its health rating as 1, "Exposure would cause irritation with only minor residual injury". Much kinder than phosphine.
So then the rub is either finding a way to get enough water into the reaction to make it cold enough, or finding another type of endothermic reaction that doesn't require so much water and would react with things readily available in the air.
So, all this to say that phosphine is nasty stuff and that endothermic reactions can be spontaneous given the right reaction conditions.
This has been your daily dose of chemistry. =)
Additionally, we are a fantasy role play and have birds that heal people by singing. Just saying.
----
In the canon of Dragonriders of Pern, it is said that Firestone is a phosphine bearing rock.
As per Wikipedia,
Phosphine is the compound with the chemical formula PH3. It is a colorless, flammable, toxic gas.
Dragons, like their fire-lizard ancestors, can breathe fire by chewing a phosphine-bearing rock, called "firestone" in the novels, which reacts with an acid in a special "second stomach" organ. This forms a volatile gas that can be exhaled at will and ignites upon contact with air. The flame is used to burn Thread from the sky before it reaches the ground. However, the chewed firestone must be expelled from the body after it is used up, for the dragons cannot digest it.
The wikipedia page on Phosphines also lists them as a fire diamond health hazard 4 (the highest rating "very deadly"), which let me tell you as a chemist is something that I would do a lot to avoid coming into contact with. It's classified as Highly flammable (F+), Very toxic (T+), Corrosive (C), and Dangerous for the environment (N).
Overexposure to phosphine gas causes nausea, vomiting, abdominal pain, diarrhea; thirst; chest tightness, dyspnea (breathing difficulty); muscle pain, chills; stupor or syncope; pulmonary edema.
--------------------
So let's start with the fact that firestone as a tool is already seeming improbable in itself.
Then I looked into "spontaneous endothermic reactions" looking for something that would occur on its own and cool down itself and the surrounding area. Turns out you can already see this happen in everyday items. Have you ever had an "instant cold pack"? Spontaneous endothermic reaction.
The general reaction used by the cold packs is:
NH4Cl + H2O
or
NH4NO3 + H2O (I think this one has been discontinued in packs due to the more health hazardous nature of NH4NO3 as opposed to NH4Cl).
NH4Cl's fire diamond gives its health rating as 1, "Exposure would cause irritation with only minor residual injury". Much kinder than phosphine.
So then the rub is either finding a way to get enough water into the reaction to make it cold enough, or finding another type of endothermic reaction that doesn't require so much water and would react with things readily available in the air.
So, all this to say that phosphine is nasty stuff and that endothermic reactions can be spontaneous given the right reaction conditions.
This has been your daily dose of chemistry. =)